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3 CLEAN-UP OF TOLUENE-CONTAMINATED SOIL AND GROUNDWATER USING SOIL VAPOR EXTRACTION David R. Hale, Senior Project Engineer Qsource Environmental Services Philip L. Hayden, Chairman of the Board Qsource Environmental Services IVliamisburg, Ohio 45342 INTRODUCTION AND BACKGROUND In 1986, a large commercial printing facility experienced a large leak of toluene solvent from a faulty pressure gauge on an underground storage tank (UST) system. Although exact amounts could not be determined, estimates of the amount spilled ranged up to 3,000 gallons. An emergency response action was undertaken to remove a quantity of heavily contaminated soil, and a site investigation to determine subsurface impacts was begun. SITE INVESTIGATION The site investigation consisted of the installation and sampling of 14 shallow groundwater monitoring wells. During the installation of these wells, it was observed that the shallow geology of the site consisted of sand and gravel outwash deposits overlying a glacial till layer. This aquitard till layer separates a thin shallow layer of groundwater from the extensive sand and gravel deep aquifer beneath the site. This deep layer is used as the sole source drinking water aquifer for a large metropolitan area. Shallow groundwater was detected at depths from 15 to 22 feet below the ground surface. The thickness of this groundwater layer ranged from approximately one to three feet. Samples of this shallow groundwater revealed toluene contamination ranging from non-detectable away from the UST spill area to above solubility limits (>450 mg/L) beneath the spill area. No observations or measurements of floating free product were made during the site investigation, although the substantial concentrations observed in several of the well samples (up to 220,000 mg/L) were undoubtedly the result of recovered free product. INITIAL GROUNDWATER REMEDIATION Based on the results of the groundwater investigation, a groundwater remediation system consisting of four recovery wells was installed. These wells were located in the area of highest groundwater contamination. Each well had a 4" diameter PVC casing, and was installed with a air-operated bladder pump to recover groundwater and free product. Recovered groundwater was then pumped to an existing solvent recovery system for treatment prior to discharge. Operation of the groundwater recovery system indicated that a total of approximately 1 gallon per minute (GPM) of groundwater was being recovered by the four wells. Based on a this recovery rate, and an average concentration of 300 mg/L toluene, this resulted in less than 0.5 gallons per day of toluene being recovered. Because of the low pumping rates, cleanup of the site and control of contamination by groundwater pump and treat was deemed not suitable. REMEDIAL ALTERNATIVE SELECTION At this stage, a decision was made to independently review the known conditions at the site and assess alternative remedial strategies for cleaning up the site. Another environmental engineering firm was retained, and after all available information on the site had been reviewed, a short-list of applicable alternatives was developed. These included: 45th Purdue Industrial Waste Conference Proceedings, © 1990 Lewis Publishers, Inc., Chelsea, Michigan 48118. Printed in U.S.A. 21
Object Description
Purdue Identification Number | ETRIWC199003 |
Title | Cleanup of toluene-contaminated soil and groundwater using soil vapor extraction |
Author |
Hale, David R. Hayden, Phillip L. |
Date of Original | 1990 |
Conference Title | Proceedings of the 45th Industrial Waste Conference |
Conference Front Matter (copy and paste) | http://e-archives.lib.purdue.edu/u?/engext,41605 |
Extent of Original | p. 21-28 |
Collection Title | Engineering Technical Reports Collection, Purdue University |
Repository | Purdue University Libraries |
Rights Statement | Digital object copyright Purdue University. All rights reserved. |
Language | eng |
Type (DCMI) | text |
Format | JP2 |
Date Digitized | 2009-08-18 |
Capture Device | Fujitsu fi-5650C |
Capture Details | ScandAll 21 |
Resolution | 300 ppi |
Color Depth | 8 bit |
Description
Title | page 21 |
Collection Title | Engineering Technical Reports Collection, Purdue University |
Repository | Purdue University Libraries |
Rights Statement | Digital copyright Purdue University. All rights reserved. |
Language | eng |
Type (DCMI) | text |
Format | JP2 |
Capture Device | Fujitsu fi-5650C |
Capture Details | ScandAll 21 |
Transcript | 3 CLEAN-UP OF TOLUENE-CONTAMINATED SOIL AND GROUNDWATER USING SOIL VAPOR EXTRACTION David R. Hale, Senior Project Engineer Qsource Environmental Services Philip L. Hayden, Chairman of the Board Qsource Environmental Services IVliamisburg, Ohio 45342 INTRODUCTION AND BACKGROUND In 1986, a large commercial printing facility experienced a large leak of toluene solvent from a faulty pressure gauge on an underground storage tank (UST) system. Although exact amounts could not be determined, estimates of the amount spilled ranged up to 3,000 gallons. An emergency response action was undertaken to remove a quantity of heavily contaminated soil, and a site investigation to determine subsurface impacts was begun. SITE INVESTIGATION The site investigation consisted of the installation and sampling of 14 shallow groundwater monitoring wells. During the installation of these wells, it was observed that the shallow geology of the site consisted of sand and gravel outwash deposits overlying a glacial till layer. This aquitard till layer separates a thin shallow layer of groundwater from the extensive sand and gravel deep aquifer beneath the site. This deep layer is used as the sole source drinking water aquifer for a large metropolitan area. Shallow groundwater was detected at depths from 15 to 22 feet below the ground surface. The thickness of this groundwater layer ranged from approximately one to three feet. Samples of this shallow groundwater revealed toluene contamination ranging from non-detectable away from the UST spill area to above solubility limits (>450 mg/L) beneath the spill area. No observations or measurements of floating free product were made during the site investigation, although the substantial concentrations observed in several of the well samples (up to 220,000 mg/L) were undoubtedly the result of recovered free product. INITIAL GROUNDWATER REMEDIATION Based on the results of the groundwater investigation, a groundwater remediation system consisting of four recovery wells was installed. These wells were located in the area of highest groundwater contamination. Each well had a 4" diameter PVC casing, and was installed with a air-operated bladder pump to recover groundwater and free product. Recovered groundwater was then pumped to an existing solvent recovery system for treatment prior to discharge. Operation of the groundwater recovery system indicated that a total of approximately 1 gallon per minute (GPM) of groundwater was being recovered by the four wells. Based on a this recovery rate, and an average concentration of 300 mg/L toluene, this resulted in less than 0.5 gallons per day of toluene being recovered. Because of the low pumping rates, cleanup of the site and control of contamination by groundwater pump and treat was deemed not suitable. REMEDIAL ALTERNATIVE SELECTION At this stage, a decision was made to independently review the known conditions at the site and assess alternative remedial strategies for cleaning up the site. Another environmental engineering firm was retained, and after all available information on the site had been reviewed, a short-list of applicable alternatives was developed. These included: 45th Purdue Industrial Waste Conference Proceedings, © 1990 Lewis Publishers, Inc., Chelsea, Michigan 48118. Printed in U.S.A. 21 |
Resolution | 300 ppi |
Color Depth | 8 bit |
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