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TREATMENT OF A WASTEWATER FROM A CHEMICALLY SYNTHESIZED PHARMACEUTICAL MANUFACTURING PROCESS WITH THE ANAEROBIC FILTER T. A. Seeler, Environmental Engineer Calocerinos and Spina Liverpool, New York 13088 J. C. Jennett, Professor Civil Engineering Department Syracuse University Syracuse, New York 13210 INTRODUCTION Anaerobic unit processes for the treatment of wastewaters have gained considerable recognition in recent years. The anaerobic processes, in some cases, have been shown to be cost effective treatment alternatives to aerobic treatment processes, particularly where highly concentrated organic wastes are concerned. The anaerobic processes are independent of oxygen transfer requirements and limitations, and hence, higher organic loadings are possible. In addition, benefits are gained from the production of a useable gas, methane, as a byproduct of a well operating anaerobic system. The subject of this study, the anaerobic filter, is one such process. In addition, this upflow, fixed medium, contact process was developed to treat wastewaters with a minimal amount of biomass production, thereby requiring less wasting of excess biomass and no solid-liquid separation step following the unit. It was the intent of this study to apply a pharamaceutical waste from a chemical synthesis manufacturing process to the anaerobic filter and evaluate: (a) the suitability of the filter to waste treatment under organic loadings typical of those which would occur during daily manufacturing operations; and (b) the maximum organic loading capacity of the filter while treating this waste. PREVIOUS STUDIES The initial laboratory scale studies of the anaerobic filter were done by Young and McCarty [1,2]. The utility of the filter was illustrated very clearly; in treating three artificial wastes, a protein-carbohydrate mixture, acetate and propionate, treatment efficiency was high. Reductions of COD were measured as high as 93.4% for the protein- carbohydrate waste with a three day hydraulic retention time and 3000 mg/l influent COD concentration, and as high as 98.4% for a volatile acid waste of 12,000 mg/l COD with a 15 day detention time [2]. It was noted that there was no need for solids wasting throughout the study, and the system required no sludge recycle. This initial study was conducted with an artificial substrate, and its real engineering applicability had yet to be proven. Others have applied the anaerobic filter, with varying success, to a variety of industrial wastes. Plummer, Malina and Eckenfelder [3] used a 16 in. (40.64 cm) high column to treat a food processing waste with an influent COD of 8500 mg/l and 687
Object Description
Purdue Identification Number | ETRIWC1978075 |
Title | Treatment of a wastewater from a chemically synthesized pharmaceutical manufacturing process with the anaerobic filter |
Author |
Seeler, T. A. Jennett, J. Charles |
Date of Original | 1978 |
Conference Title | Proceedings of the 33rd Industrial Waste Conference |
Conference Front Matter (copy and paste) | http://e-archives.lib.purdue.edu/u?/engext,27312 |
Extent of Original | p. 687-695 |
Collection Title | Engineering Technical Reports Collection, Purdue University |
Repository | Purdue University LIbraries |
Rights Statement | Digital object copyright Purdue University. All rights reserved. |
Language | eng |
Type (DCMI) | text |
Format | JP2 |
Date Digitized | 2009-06-22 |
Capture Device | Fujitsu fi-5650C |
Capture Details | ScandAll 21 |
Resolution | 300 ppi |
Color Depth | 8 bit |
Description
Title | page0687 |
Collection Title | Engineering Technical Reports Collection, Purdue University |
Repository | Purdue University Libraries |
Rights Statement | Digital copyright Purdue University. All rights reserved. |
Language | eng |
Type (DCMI) | text |
Format | JP2 |
Capture Device | Fujitsu fi-5650C |
Capture Details | ScandAll 21 |
Transcript | TREATMENT OF A WASTEWATER FROM A CHEMICALLY SYNTHESIZED PHARMACEUTICAL MANUFACTURING PROCESS WITH THE ANAEROBIC FILTER T. A. Seeler, Environmental Engineer Calocerinos and Spina Liverpool, New York 13088 J. C. Jennett, Professor Civil Engineering Department Syracuse University Syracuse, New York 13210 INTRODUCTION Anaerobic unit processes for the treatment of wastewaters have gained considerable recognition in recent years. The anaerobic processes, in some cases, have been shown to be cost effective treatment alternatives to aerobic treatment processes, particularly where highly concentrated organic wastes are concerned. The anaerobic processes are independent of oxygen transfer requirements and limitations, and hence, higher organic loadings are possible. In addition, benefits are gained from the production of a useable gas, methane, as a byproduct of a well operating anaerobic system. The subject of this study, the anaerobic filter, is one such process. In addition, this upflow, fixed medium, contact process was developed to treat wastewaters with a minimal amount of biomass production, thereby requiring less wasting of excess biomass and no solid-liquid separation step following the unit. It was the intent of this study to apply a pharamaceutical waste from a chemical synthesis manufacturing process to the anaerobic filter and evaluate: (a) the suitability of the filter to waste treatment under organic loadings typical of those which would occur during daily manufacturing operations; and (b) the maximum organic loading capacity of the filter while treating this waste. PREVIOUS STUDIES The initial laboratory scale studies of the anaerobic filter were done by Young and McCarty [1,2]. The utility of the filter was illustrated very clearly; in treating three artificial wastes, a protein-carbohydrate mixture, acetate and propionate, treatment efficiency was high. Reductions of COD were measured as high as 93.4% for the protein- carbohydrate waste with a three day hydraulic retention time and 3000 mg/l influent COD concentration, and as high as 98.4% for a volatile acid waste of 12,000 mg/l COD with a 15 day detention time [2]. It was noted that there was no need for solids wasting throughout the study, and the system required no sludge recycle. This initial study was conducted with an artificial substrate, and its real engineering applicability had yet to be proven. Others have applied the anaerobic filter, with varying success, to a variety of industrial wastes. Plummer, Malina and Eckenfelder [3] used a 16 in. (40.64 cm) high column to treat a food processing waste with an influent COD of 8500 mg/l and 687 |
Resolution | 300 ppi |
Color Depth | 8 bit |
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