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POLLUTION POTENTIALS OF COAL GASIFICATION PLANTS Stanley L. Klemetson, Assistant Professor Department of Civil Engineering North Dakota State University Fargo, North Dakota 58102 INTRODUCTION Since the time that natural gas and oil replaced coal as a major source of power, our needs for energy have continued to rise. However, domestic production of natural gas is on the decline, and this has created an energy crisis in the United States. While some of our needs for natural gas will be met with imported products, the production of synthetic natural gas (SNG) by the coal gasification process is also being considered as a part of the solution. This would allow the production of a clean fuel from a pollutirig fuel such as coal. A primary concern is that the treatment and/or conversion process that generates the clean fuel does not itself become a major pollution source. While the potential pollutants can be expressed in any or all of the three possible states of air emissions, solid wastes and liquid effluents, all of them ultimately contribute to the wastewater effluents of the plant and its site. Energy production utilizing a coal gasification process to produce a high-Btu SNG with a heating value of about 970 Btu/scf will become a reality in the United States within the next few years. The enactment of increasingly stringent environmental legislation requires that information be made available on the types of wastes to be generated, the environmental effects of these wastes, and the best available treatment technology. Since coal gasification plants are net consumers of water, it is also important to assess the wastes from the standpoint of water reuse potential. The proposed plants will be operating under widely different climatic conditions, and this could have a significant effect on the choice of wastewater treatment processes. A variety of processes have been developed to produce both high-Btu and low-Btu SNG (Table 1). Each of the gasification processes has a different configuration of unit operations, but the resulting wastewater effluents are somewhat similar. Since the Lurgi gasification process is currently available and is being planned for several areas in the northern Great Plains region of the United States, this paper has been limited to this process and to North Dakota lignite coal. However, much of the information will be applicable to the other processes also. The purpose of this paper is: (a) to discuss the Lurgi gasification unit operations and potential sources of wastewater effluents, (b) to assess the pollutants present in the feed coals, (c) to review the characteristics of selected process streams and waste effluents, (d) to review the available treatment technologies, and (e) to assess the effects of climatic conditions on these treatment methods. LURGI GASIFICATION PROCESS The Lurgi coal gasification plants planned for construction in the United States are being designed to produce about 250 x 106 scfd of medium- to high-Btu SNG that will yield about 970 Btu/scf. The average consumption of coal in these plants is about 1000 to 1500 tons per hour, and the average annual usage of raw water is about 17,500 ac-ft. The plants will be required to meet strict air, solid waste and water pollution regulations, and will be expected to practice conservation by a reasonable water reuse program. The complexity of the coal gasification process requires that major (Operations be described in terms of modules that will allow for the analysis of process streams and emissions. A list of the modules and their typical effluents is shown in Table II, and a simplified block diagram of the Lurgi gasification plant processes and effluent sources is shown in Figure 1. The various process and effluent streams have been left off for clarity. 63
Object Description
Purdue Identification Number | ETRIWC197606 |
Title | Pollution potentials of coal gasification plants |
Author | Klemetson, Stanley L. |
Date of Original | 1976 |
Conference Title | Proceedings of the 31st Industrial Waste Conference |
Conference Front Matter (copy and paste) | http://e-archives.lib.purdue.edu/u?/engext,27048 |
Extent of Original | p. 63-76 |
Collection Title | Engineering Technical Reports Collection, Purdue University |
Repository | Purdue University Libraries |
Rights Statement | Digital object copyright Purdue University. All rights reserved. |
Language | eng |
Type (DCMI) | text |
Format | JP2 |
Date Digitized | 2009-07-07 |
Capture Device | Fujitsu fi-5650C |
Capture Details | ScandAll 21 |
Resolution | 300 ppi |
Color Depth | 8 bit |
Description
Title | page 63 |
Collection Title | Engineering Technical Reports Collection, Purdue University |
Repository | Purdue University Libraries |
Rights Statement | Digital object copyright Purdue University. All rights reserved. |
Language | eng |
Type (DCMI) | text |
Format | JP2 |
Capture Device | Fujitsu fi-5650C |
Capture Details | ScandAll 21 |
Transcript | POLLUTION POTENTIALS OF COAL GASIFICATION PLANTS Stanley L. Klemetson, Assistant Professor Department of Civil Engineering North Dakota State University Fargo, North Dakota 58102 INTRODUCTION Since the time that natural gas and oil replaced coal as a major source of power, our needs for energy have continued to rise. However, domestic production of natural gas is on the decline, and this has created an energy crisis in the United States. While some of our needs for natural gas will be met with imported products, the production of synthetic natural gas (SNG) by the coal gasification process is also being considered as a part of the solution. This would allow the production of a clean fuel from a pollutirig fuel such as coal. A primary concern is that the treatment and/or conversion process that generates the clean fuel does not itself become a major pollution source. While the potential pollutants can be expressed in any or all of the three possible states of air emissions, solid wastes and liquid effluents, all of them ultimately contribute to the wastewater effluents of the plant and its site. Energy production utilizing a coal gasification process to produce a high-Btu SNG with a heating value of about 970 Btu/scf will become a reality in the United States within the next few years. The enactment of increasingly stringent environmental legislation requires that information be made available on the types of wastes to be generated, the environmental effects of these wastes, and the best available treatment technology. Since coal gasification plants are net consumers of water, it is also important to assess the wastes from the standpoint of water reuse potential. The proposed plants will be operating under widely different climatic conditions, and this could have a significant effect on the choice of wastewater treatment processes. A variety of processes have been developed to produce both high-Btu and low-Btu SNG (Table 1). Each of the gasification processes has a different configuration of unit operations, but the resulting wastewater effluents are somewhat similar. Since the Lurgi gasification process is currently available and is being planned for several areas in the northern Great Plains region of the United States, this paper has been limited to this process and to North Dakota lignite coal. However, much of the information will be applicable to the other processes also. The purpose of this paper is: (a) to discuss the Lurgi gasification unit operations and potential sources of wastewater effluents, (b) to assess the pollutants present in the feed coals, (c) to review the characteristics of selected process streams and waste effluents, (d) to review the available treatment technologies, and (e) to assess the effects of climatic conditions on these treatment methods. LURGI GASIFICATION PROCESS The Lurgi coal gasification plants planned for construction in the United States are being designed to produce about 250 x 106 scfd of medium- to high-Btu SNG that will yield about 970 Btu/scf. The average consumption of coal in these plants is about 1000 to 1500 tons per hour, and the average annual usage of raw water is about 17,500 ac-ft. The plants will be required to meet strict air, solid waste and water pollution regulations, and will be expected to practice conservation by a reasonable water reuse program. The complexity of the coal gasification process requires that major (Operations be described in terms of modules that will allow for the analysis of process streams and emissions. A list of the modules and their typical effluents is shown in Table II, and a simplified block diagram of the Lurgi gasification plant processes and effluent sources is shown in Figure 1. The various process and effluent streams have been left off for clarity. 63 |
Resolution | 300 ppi |
Color Depth | 8 bit |
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